Citation: U.S. EPA. June 1999 Compendium of Methods for Inorganic Air Pollutants Page 5.0-1 Chapter IO-5 SAMPLING AND ANALYSIS FOR ATMOSPHERIC MERCURY Method IO-5 SAMPLING AND ANALYSIS … Hg analysis, Do you need to comply with a regulatory method? 1999 Method 1631-B – Included the analysis of effluent matrices. If your sample is a liquid (i.e., wastewater or drinking water) then you will be best served by one of the chemical reduction techniques (CVAA or CVAF). ----- 1 INTRODUCTION This preliminary study on methods of analysis for mercury in water was conducted to develop further information on the ability of the analytical methods to measure total mercury, i.e., organic plus inorganic CVAF instruments are available in two configurations; one employing simple atomic fluorescence and one that employs gold amalgamation to preconcentrate mercury prior to measurement by atomic fluorescence. If your sample is a solid, you have the choice of digesting the sample, then analyzing it by CVAA or CVAF. The detection limit via the simple fluorescence approach is about 0.2 ppt whereas using the preconcentration with fluorescence detection can be as low as 0.02 ppt. necessary to determine those most suited to this analysis. Each technique has advantages and disadvantages, I'll review each technique and provide tips for choosing the right one for various situations. CVAA, As in the case of fly ash, the mercury content of gypsum varies depending on the characteristics of the power plant, the nature of the coal burned and the performance of the FGD plant. 1974). Analytical methods There are different methods of separating mercury from the sample and for measuring the levels of mercury. The PerkinElmer FIMS 100 is a compact, easy-to-operate mercury analyzer with an integrated flow injection system for cold vapor mercury AA. Analytical techniques for measuring mercury include cold vapor atomic absorption spectroscopy (CVAA), cold vapor atomic fluorescence spectroscopy (CVAF), and direct analysis by thermal decomposition. EPA draft Method 1630 for methyl mercury analysis is a very sensitive technique using an atomic fluorescence detector for sub nanogram per liter quantitation of methyl mercury in waters. For example, if your lab is required to analyze samples using EPA method 245.1, then you will need to use the technique CVAA. 1) If sampling equipment other than the sample bottles is required, follow these instructions: a) Use the Traditional methods for Hg analysis require a separate sample preparation combined with a single-element Hg analyzer, which reduces sample throughput and productivity. Alternatively, you may be able to skip the digestion step and go with direct analysis by thermal decomposition. By answering a few simple questions, you will be guided in the direction of the techique which is right for you. Analytical techniques for measuring mercury include cold vapor atomic absorption spectroscopy (CVAA), cold vapor atomic fluorescence spectroscopy (CVAF), and direct analysis by thermal decomposition. David Pfeil on Feb 10, 2012 3:31:00 PM. Cross-reference of Lab Analysis Codes to Methods Used MRL code NWIS code Description Detection Limit Method Reference Water FTHG P50287 Filtered total mercury … Mason, OH 45040. 3.0 Safety Issues: Specific safety concerns for each chemical can be found in the Material Safety Data Sheets for that chemical, all of which are located in the laboratory. Sampling Instructions for Low Level Mercury Analysis (Method 1631) Please read very carefully prior to sample collection. mercury have been developed. If your lab is not constrained by a regulatory method, the driving force more than likely be such things as: The characteristics of your sample matrix (for example, is it a solid or a liquid), The detection limits you need to reach in that matrix, Your preferences regarding digesting the sample or not. Both of these ICP test methods can be performed on solid or liquid samples. 13. Because direct analysis is limited to a relatively small quantity of sample (about 1 g), nonhomogeneous samples may be best dealt with by digesting a larger quantity of sample followed by analysis using CVAA or CVAF. There are many insoluble salts of lead, leading to the earliest known methods Flameless AAS is the NIOSH-recommended method of determining levels of mercury in expired air (NIOSH 1994). For labs that analyze large numbers of solid samples, or that would rather not perform the digestion associated with CVAA and CVAF, direct analysis may be ideal. 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